cis-Diiodido(N,N,N′,N′-tetramethylethylenediamine-κ2 N,N′)palladium(II)
نویسندگان
چکیده
In the title complex, cis-[PdI(2)(C(6)H(16)N(2))], the Pd(II) atom lies on a crystallographic twofold rotation axis and is four-coordinated by the two N atoms of a chelating N,N,N',N'-tetra-methyl-ethylenediamine ligand [Pd-N = 2.125 (3) Å] and two I atoms [Pd-I = 2.5833 (4) Å], displaying a distorted square-planar geometry (r.m.s. deviation = 0.005 Å), imposed by the small bite of the chelating ligand [N-Pd-N angle = 84.68 (18)°].
منابع مشابه
Dicarbonyldichlorido(N,N,N′,N′-tetramethylethylenediamine)ruthenium(II)
In the title compound, [RuCl(2)(C(6)H(16)N(2))(CO)(2)], the geometry around the Ru(II) atom is a distorted RuC(2)N(2)Cl(2) octa-hedron, with pairs of C and Cl atoms trans to each other and the N atoms of the bidentate ligand in a cis conformation. The five-membered chelate ring is puckered on the C-C bond.
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